Synthesis of tetradentate bisamino-bisthiol complexes of oxorhenium (V) as structural mimics of steroids

Y Sugano, JA Katzenellenbogen

Index: Sugano, Yuichi; Katzenellenbogen, John A. Bioorganic and Medicinal Chemistry Letters, 1996 , vol. 6, # 4 p. 361 - 366

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Citation Number: 20

Abstract

Two tetradentate chelate systems have been synthesized in order to prepare metal complexes with oxorhenium (V) whose structures will mimic that of steroids. The chelate system with amide/amine/thioether/thiol donor sites failed to give a stable complex, but the corresponding diamine chelate gave a stable complex.

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