Journal of the American Chemical Society

The Effect of Substituent Groups upon the Course of the Condensation Reaction between Benzenediazonium Salts and Phenols1

JC Colbert, RM Lacy

Index: Colbert; Lacy Journal of the American Chemical Society, 1946 , vol. 68, p. 270

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Citation Number: 18

Abstract

In 1890 Hirsch3 reported that diazo compounds can be extracted from aqueous solution by phenols and upon heating react to form hydroxybiphenyls. The reaction medium was kept acid so that no azo-type coupling occurred. Norris, Macintire and Corse4 later studied this reaction, reporting similar results together with the formation clf a black, brittle material probably formed by the introduction of several phenyl groups into the diazo nucleus. ...

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