Halogen Substituted Vinyltrichlorosilanes and Ethyltrichlorosilanes

CL Agre, W Hilling

Index: Agre, C. L.; Hilling, W. Journal of the American Chemical Society, 1952 , vol. 74, p. 3895 - 3899

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Citation Number: 26

Abstract

High temperature reaction of a mixture of trichloroethylene aiid trichlorosilane gives predominately P, P-dichlorovinyltrichlorosilane instead of cy, 8-dichloroviiiyltrichlorosilane previously reported.@-Chloroethyltrichlorosilane is much more reactive upon pyrolysis and also when treated with quinoline than is a-chloroethyltrichlorosilane, and gives mainly silicon tetrachloride and viiiyltrichlorosilane. Treatment of a, P-dichloroethyltrichlorosilane ...