Molecular Diversity 2006-02-01

Three-component reaction between triphenylphosphine, dialkyl acetylenedicarboxylates and urea or N-methylurea.

Issa Yavari, Nader Zabarjad-Shiraz

Index: Mol. Divers. 10(1) , 23-7, (2006)

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Abstract

The stabilized phosphoranes, obtained from the three-component reaction between dialkyl acetylenedicarboxylates and urea or N-methylurea in the presence of triphenylphosphine, undergo a smooth reaction in boiling toluene to produce iminophosphoranes in good yields. Under the same reaction conditions, the phosphorane obtained from N-methylurea and dimethyl acetylenedicarboxylate yields methyl 1-methyl-2,6-dioxo-1,2,3,6-tetrahydro-pyrimidine-4-carboxylate.

Related Compounds

  • 1-Methylurea
  • Dimethyl but-2-yne...

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