Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by Chiral O,N,O-tridentate Phenol Ligands Derived From Camphor.
Dong-Sheng Lee, Shu-Ming Chang, Chun-Ying Ho, Ta-Jung Lu
Index: Chirality 28 , 65-71, (2016)
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Abstract
Chiral O,N,O-tridentate phenol ligands bearing a camphor backbone were found to be effective chiral catalysts for the enantioselective addition of diethylzinc to aromatic aldehydes, resulting in high enantioselectivities (80-95% ee) at room temperature.© 2015 Wiley Periodicals, Inc.
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