Hydrolysis of imidazole-containing amide acetals

RS Brown, JG Ulan

Index: Brown, R. S.; Ulan, J. G. Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2382 - 2388

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Citation Number: 14

Abstract

Summary Hole formation (ionization) is predicted to accelerate a variety of pericyclic reactions, especially those in which highly nonsynchronous transition states are readily accessible. The cation-radical Diels-Alder reaction path is characterized as concerted and highly nonsynchronous. The reaction path for the [2+ 11 cycloaddition emerges as a two- step sequence. An intermediate long-bond cyclobutane cation radical is formed via a ...