Organic Letters 2003-12-25

Direct carbamoylation of alkenyl halides.

Robert F Cunico, Bikash C Maity

Index: Org. Lett. 5 , 4947, (2003)

Full Text: HTML

Abstract

Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text]

Related Compounds

  • Bis(tri-t-butylpho...

Related Articles:

Pd/P(t-Bu)(3): a mild and general catalyst for Stille reactions of aryl chlorides and aryl bromides.

2002-06-05

[J. Am. Chem. Soc. 124 , 6343, (2003)]

Sequential assembly strategy for tetrasubstituted olefin synthesis using vinyl 2-pyrimidyl sulfide as a platform.

2004-09-29

[J. Am. Chem. Soc. 126 , 11778, (2004)]

Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides.

2002-09-06

[J. Org. Chem. 67 , 6479, (2002)]

Chemoselective and regiospecific Suzuki coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes at room temperature.

2010-08-18

[J. Am. Chem. Soc. 132 , 11033, (2010)]

Negishi, E.-I.; Shi, J.-C.; Zeng, X.

[Tetrahedron 61 , 9886, (2005)]

More Articles...