Chemical Communications 2011-06-28

One pot iridium-catalyzed asymmetrical double allylations of sodium sulfide: a fast and economic way to construct chiral C2-symmetric bis(1-substituted-allyl)sulfane.

Gregory P Mueller, William J Driscoll

Index: Chem. Commun. (Camb.) 47(24) , 6969-71, (2011)

Full Text: HTML

Abstract

One pot asymmetrical double allylations of sodium sulfide catalyzed by an iridium complex along with a combination of caesium fluoride and water in dichloromethane have been realized and the double allylation products with two C-S bond chiral centers were obtained in 67-99% yields with b/l 81/19-99/1, dr 85/15-99/1, and 96-99% ee.This journal is © The Royal Society of Chemistry 2011

Related Compounds

  • Caesium fluoride

Related Articles:

Computational investigation of a new ion-pair receptor for calix[4]pyrrole.

2012-06-01

[J. Mol. Model. 18(6) , 2291-9, (2012)]

[Summation of GABA- and glutamate-mediated currents in rat cortical neurons].

2012-12-01

[Ross. Fiziol. Zh. Im. I. M. Sechenova 98(12) , 1490-506, (2012)]

One-step synthesis of racemic α-amino acids from aldehydes, amine components, and gaseous CO2 by the aid of a bismetal reagent.

2013-01-14

[Chemistry 19(3) , 1123-8, (2013)]

Control of phosphoryl migratory transesterifications allows regioselecive access to sugar phosphates.

2013-01-18

[Org. Lett. 15(2) , 346-9, (2013)]

Caesium fluoride-promoted Stille coupling reaction: an efficient synthesis of 9Z-retinoic acid and its analogues using a practical building block.

2008-12-21

[Chem. Commun. (Camb.) (47) , 6330-2, (2008)]

More Articles...