TEMPO mediated oxidation of fluorinated alcohols to carboxylic acids

J Ignatowska, O Shyshkov, T Zipplies, K Hintzer…

Index: Ignatowska, Jolanta; Shyshkov, Oleg; Zipplies, Tilman; Hintzer, Klaus; Roeschenthaler, Gerd-Volker Journal of Fluorine Chemistry, 2012 , vol. 141, p. 35 - 40

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Abstract

The synthesis of fluorinated carboxylic acids and derivatives thereof has attracted much attention due to their manifold industrial applications for instance as emulsifying agents [1]. These compounds can be prepared by electrolytic fluorination of the parent hydrocarbon compounds [2], oxidative cleavage of perfluorinated olefins [3], by ring-opening addition of hexafluorooxetane to fluorine containing acyl fluorides [4] or in reactions of perfluoroalkyl iodides with carbon dioxide [5].

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