The Journal of Organic Chemistry

Electroorganic reactions. 31. Quinonemethide radical anions and dianions. Their cathodic generation and reactivity

MOF Goulart, JHP Utley

Index: Goulart, Marilia O. F.; Utley, James H. P. Journal of Organic Chemistry, 1988 , vol. 53, # 11 p. 2520 - 2525

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Citation Number: 18

Abstract

The cathodic reactions of a number of relatively stable quinonemethides have been examined in detail by cyclic voltammetry, controlled potential coulometry, and rigorous product analysis following preparative-scale electrolyses. The results of cyclic voltammetric experiments differ in some respects from those of earlier polarographic work. The lifetimes of the electrogenerated radical-anions and dianions, in the absence of added electrophile, ...

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