Chemistry–A European Journal

Hydrogenolysis of benzylic alcohols on rhodium catalysts

VS Ranade, R Prins

Index: Ranade, Vidyadhar S.; Prins, Roel Chemistry - A European Journal, 2000 , vol. 6, # 2 p. 313 - 320

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Citation Number: 28

Abstract

Abstract Carbon-supported rhodium catalysts yield substantially more of the product of C− O bond scission (3, see figure) than the alumina-supported rhodium catalysts in the liquid- phase hydrogenation of 1-indanol (1). The high C− O bond scission capability of the carbon- supported catalysts is due to direct hydrogenolysis that occurs on the carbon support with spillover hydrogen.

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