Thermolysis of N, N-dihalo derivatives of bridgehead and neopentylamines to the corresponding halides

JT Roberts, BR Rittberg, P Kovacic…

Index: Roberts, John T.; Rittberg, Barry R.; Kovacic, Peter; Scalzi, Francis V.; Seely, Michael J. Journal of Organic Chemistry, 1980 , vol. 45, # 26 p. 5239 - 5243

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Abstract

dichloroamines (RNC12) under pyrolytic conditions revealed various reaction pathways: alkene, chloroimine, or nitrile formation'from simple alkyl types and azo products from perfluoroalky18 or arylD groups. The Stieglitz rearrangement entails the thermal conversion of N, N-dichlorotritylamine to benzophenone anil. 1 This report deals with a novel pyrolytic reaction of N, N-dihalo derivatives of bridgehead and neopentyl amines involving ...

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