Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2007-04-01

Spectral studies on Co(II), Ni(II) and Cu(II) complexes with thiosemicarbazone (L1) and semicarbazone (L2) derived from 2-acetyl furan.

Sulekh Chandra, Anil Kumar

Index: Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 66(4-5) , 1347-51, (2007)

Full Text: HTML

Abstract

Co(II), Ni(II) and Cu(II) complexes are synthesized with thiosemicarbazone (L1) and semicarbazone (L2) derived from 2-acetyl furan. These complexes are characterized by elemental analysis, molar conductance, magnetic susceptibility measurements, mass, IR, electronic and EPR spectral studies. The molar conductance measurements of the complexes in DMSO correspond to non-electrolytic nature except Ni(L)2(NO3)2, which is 1:2 electrolyte. All the complexes are of high-spin type. On the basis of spectral studies an octahedral geometry may be assigned for Co(II) and Ni(II) complexes except nitrato complexes of Ni(II) which is of tetrahedral geometry, whereas tetragonal geometry for Cu(II) complexes.

Related Compounds

  • 1-(Furan-2-yl)etha...

Related Articles:

Quantification of furanic derivatives in fortified wines by a highly sensitive and ultrafast analytical strategy based on digitally controlled microextraction by packed sorbent combined with ultrahigh pressure liquid chromatography.

2015-02-13

[J. Chromatogr. A. 1381 , 54-63, (2015)]

Dose-dependent increase in 2,5-hexanedione in the urine of workers exposed to n-hexane.

1991-01-01

[Int. Arch. Occup. Environ. Health 63(4) , 285-91, (1991)]

2-Acetylfuran, a confounder in urinalysis for 2,5-hexanedione as an n-hexane exposure indicator.

1991-01-01

[Int. Arch. Occup. Environ. Health 63(3) , 213-9, (1991)]

[Acute hepatitis in subjects exposed to 2-acetylfuran and hydrazine].

1983-01-01

[Med. Lav. 74(4) , 284-90, (1983)]

Comparison of 2-acetylfuran formation between ribose and glucose in the Maillard reaction.

2008-12-24

[J. Agric. Food Chem. 56(24) , 11997-2001, (2008)]

More Articles...