Novel role of carbon monoxide as a Lewis acid catalyst for Friedel-Crafts reaction

S Ogoshi, H Nakashima, K Shimonaka…

Index: Ogoshi; Nakashima; Shimonaka; Kurosawa Journal of the American Chemical Society, 2001 , vol. 123, # 35 p. 8626 - 8627

Full Text: HTML

Citation Number: 13

Abstract

The Friedel-Crafts reaction, in which a Lewis acid plays a crucial role to improve the efficiency of the reaction, is the most important and traditional method to introduce an alkyl group into an aromatic ring. 1 Thus far, a gaseous Lewis acid, such as BF3, has been employed as a very useful Lewis acid due to the simple separation from the reaction mixture, despite its corrosive and expensive nature. Thus, a gaseous, noncorrosive, and ...

Related Articles:

Efficient H/D Exchange Reactions of Alkyl??Substituted Benzene Derivatives by Means of the Pd/C–H2–D2O System

[Esaki, Hiroyoshi; Aoki, Fumiyo; Umemura, Miho; Kato, Masatsugu; Maegawa, Tomohiro; Monguchi, Yasunari; Sajiki, Hironao Chemistry - A European Journal, 2007 , vol. 13, # 14 p. 4052 - 4063]

Multimetallic Ir–Sn 3-catalyzed substitution reaction of π-activated alcohols with carbon and heteroatom nucleophiles

[Maity, Arnab Kumar; Chatterjee, Paresh Nath; Roy, Sujit Tetrahedron, 2013 , vol. 69, # 2 p. 942 - 956]

Ultrasound promoted Barbier reactions and Csp 3–Csp 2 Stille coupling for the synthesis of diarylmethanes and substituted benzophenones

[Ocampo, Romina A.; Koll, Liliana C.; Mandolesi, Sandra D. Ultrasonics Sonochemistry, 2013 , vol. 20, # 1 p. 40 - 46]

An Efficient and Inexpensive Catalyst System for Friedel??Crafts Alkylation of Aromatic Compounds with Benzyl and Allyl Alcohols

[Li, Jin-Heng; Liu, Wen-Jie; Yin, Du-Lin Synthetic Communications, 2004 , vol. 34, # 17 p. 3161 - 3165]

Iron (III) amine-bis (phenolate) complexes as catalysts for the coupling of alkyl halides with aryl Grignard reagents

[Chowdhury, Rajoshree Roy; Crane, Angela K.; Fowler, Candace; Kwong, Philip; Kozak, Christopher M. Chemical Communications, 2008 , # 1 p. 94 - 96]

More Articles...