Journal of the American Chemical Society

Chemical model studies for the mechanism of vitamin K epoxide reductase

RB Silverman

Index: Silverman Journal of the American Chemical Society, 1981 , vol. 103, # 19 p. 5939 - 5941

Full Text: HTML

Citation Number: 72

Abstract

11 9 spectra, and IR" spectrum. The stereochemistry drawn for 8 was derived from the known reaction of thiols with epoxides to yield exclusive anti-@-hydroxy sulfides14 (and from the isolation of the same compound with base catalysis as described below). When the reaction was allowed to proceed for 6 h, a 52% yield of 8 and a 40% yield of 2, 3-dimethyl-1, 4-naphthoquinone (9), identified by comparison of its NMR and IR spectra with those of an ...

Related Articles:

Chromium (VI) oxide catalyzed oxidation of sulfides to sulfones with periodic acid

[Yamazaki, Shigekazu Tetrahedron Letters, 2001 , vol. 42, # 19 p. 3355 - 3357]

Synthesis and redox potentials of methylated vitamin K derivatives

[Schmid, Ralf; Goebel, Friederike; Warnecke, Andre; Labahn, Andreas Journal of the Chemical Society. Perkin Transactions 2, 1999 , # 6 p. 1199 - 1202]

t??Butyl hydroperoxide oxidative dealkylation of hydroquinone ethers to 1, 4??quinones

[Wojtowicz, Halina; Mlochowski, Jacek; Syper, Ludwik; Yadav, Hardeo Synthetic Communications, 2006 , vol. 36, # 14 p. 1991 - 2000]

The synthesis of lignin model substances: 5-hydroxyvanillin and 5-hydroxyacetoguaiacone

[Bansal; Thapliyal; Khanna Synthetic Communications, 1995 , vol. 25, # 11 p. 1669 - 1675]

Study of radical decarboxylation toward functionalization of naphthoquinones

[Commandeur, Claude; Chalumeau, Celine; Dessolin, Jean; Laguerre, Michel European Journal of Organic Chemistry, 2007 , # 18 p. 3045 - 3052]

More Articles...