The Decomposition of Arenediazonium Tetrafluoroborates with Halo-and Azidotrimethylsilanes in Nonaqueous Solvents

T Keumi, T Umeda, Y Inoue, H Kitajima

Index: Keumi, Takashi; Umeda, Toshiaki; Inoue, Yoshinori; Kitajima, Hidehiko Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 1 p. 89 - 95

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Citation Number: 21

Abstract

The reaction of arenediazonium tetrafluoroborates with chlorotrimethylsilane in a tetrahydrofuran/N, N-dimethylformamide (DMF)(5v/3v) solution afforded the protodediazotization products in high yields. The reactions of the diazonium salts with halotrimethylsilanes in DMF were found to give the corresponding haloarenes. Among the halodediazotization reactions, the iododediazotization with iodotrimethylsilane proceeded ...

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