Cross-coupling reaction of pentacoordinate alkenylsilicates with organic halides and triflates catalyzed by a palladium complex

…, C Murakami, H Aihara, E Komori, S Kohra…

Index: Hojo, Makoto; Murakami, Chikara; Aihara, Hidenori; Komori, Ei-ichi; Kohra, Shinya; et al. Bulletin de la Societe Chimique de France, 1995 , vol. 132, p. 499 - 508

Full Text: HTML

Citation Number: 18

Abstract

Résumé/Abstract Isolated pentacoordinate alkoxy-substituted alkenylsilicates, are readily prepared by mixing alkenyltrialkoxy-silane, catechol and triethylamine at room temperature. Cross-coupling reactions of these alkenylsilicates with organic halides or triflates are catalyzed by a palladium complex and proceed very smoothly and cleanly to give the corresponding alkenes. The cross-coupling reactions could be also attained by a one pot ...

Related Articles:

The. beta.-effect: changing the ligands on silicon

[Brook, Michael A.; Neuy, Axel Journal of Organic Chemistry, 1990 , vol. 55, # 11 p. 3609 - 3616]

The. beta.-effect: changing the ligands on silicon

[Brook, Michael A.; Neuy, Axel Journal of Organic Chemistry, 1990 , vol. 55, # 11 p. 3609 - 3616]

The effect of substituents at silicon on the cross-metathesis of trisubstituted vinylsilanes with olefins

[Pietraszuk, Cezary; Fischer, Helmut; Rogalski, Szymon; Marciniec, Bogdan Journal of Organometallic Chemistry, 2005 , vol. 690, # 24-25 p. 5912 - 5921]

More Articles...