Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2003-05-01

In situ UV-visible spectroelectrochemical studies on the copolymerization of diphenylamine with ortho-methoxy aniline.

P Santhosh, A Gopalan, T Vasudevan

Index: Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 59(7) , 1427-39, (2003)

Full Text: HTML

Abstract

UV-visible spectroelectrochemical studies on copolymerization of diphenylamine (DPA) with ortho-methoxy aniline (OMA) were carried out for different feed ratios of DPA and OMA using indium tin oxide (ITO)-coated glass as working electrode. The UV-visible spectra show clear dependencies on the molar feed composition of DPA or OMA used in electropolymerization. Derivative cyclic voltabsorptogram (DCVA) was deduced at the wavelengths corresponding to the absorption by the intermediate species and used to confirm the intermediates generated during the electropolymerization. The composition of DPA and OMA in the copolymer for the copolymers synthesized with different molar feed ratios of DPA and OMA was determined by UV-visible spectroscopy. Reactivity ratios of DPA and OMA were deduced by using Fineman-Ross and Kelen-Tudos methods and correlated with spectroelectrochemical results.

Related Compounds

  • 2-Anisidine

Related Articles:

Toxicological assessment of kretek cigarettes: Part 1: background, assessment approach, and summary of findings.

2014-12-01

[Regul Toxicol Pharmacol 70 Suppl 1 , S2-14, (2014)]

Monoarylamines in the general population--a cross-sectional population-based study including 1004 Bavarian subjects.

2009-05-01

[Int. J. Hyg. Environ. Health 212(3) , 298-309, (2009)]

Redox cycling in the metabolism of the environmental pollutant and suspected human carcinogen o-anisidine by rat and rabbit hepatic microsomes.

2008-08-01

[Chem. Res. Toxicol. 21(8) , 1610-21, (2008)]

Identification of a genotoxic mechanism for the carcinogenicity of the environmental pollutant and suspected human carcinogen o-anisidine.

2005-09-20

[Int. J. Cancer 116(5) , 667-78, (2005)]

Dynamic scale theory for characterizing surface morphology of layer-by-layer films of poly(o-methoxyaniline).

2004-05-01

[J. Nanosci. Nanotechnol. 4(5) , 548-52, (2004)]

More Articles...