Synthesis of cyclic N??nitrourethanes by the simultaneous oxidative desulfurization and nitration of cyclic thiourethanes

RL Willer, CG Campbell…

Index: Willer, Rodney L.; Campbell, Christopher G.; Storey, Robson F. Journal of Heterocyclic Chemistry, 2012 , vol. 49, # 2 p. 421 - 423

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Abstract

Abstract The reaction of five-and six-membered cyclic thiourethanes with acetyl nitrate results in a vigorous reaction that generates copious amounts of red–brown nitrogen oxide fumes and produces the corresponding cyclic N-nitrourethanes in high yields (> 95%). The overall yield of the cyclic N-nitrourethanes starting from an aminoalcohol using the “thiourethane” route is superior to the conventional route going through the cyclic ...

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