A new method for the synthesis of trifluoromethylating agents—Diaryltrifluoromethylsulfonium salts

…, RK Orlova, BG Deryabkin, YL Yagupolskii

Index: Yagupolskii, Lev M.; Matsnev, Andrej V.; Orlova, Raisa K.; Deryabkin, Boris G.; Yagupolskii, Yurii L. Journal of Fluorine Chemistry, 2008 , vol. 129, # 2 p. 131 - 136

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Citation Number: 36

Abstract

Download PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... A new synthetic method has been developed to prepare diaryltrifluoromethylsulfonium salts from diaryldifluorosulfuranes by the action of Me 3 SiCF 3 /F − . This reaction is the transformation of nucleophilic trifluoro-methylating reagent into electrophilic one. ... Organic compounds containing trifluoromethyl group ...