Bulletin of the Chemical Society of Japan

Friedel-Crafts Aralkylation. II. The AlCl 3· CH 3 NO 2-catalyzed Phenethylation of Benzene and Toluene with 2-Arylethyl Chlorides in a Nitromethane Solution

M Ichii

Index: Ichii,M. Bulletin of the Chemical Society of Japan, 1972 , vol. 45, # 9 p. 2810 - 2813

Full Text: HTML

Citation Number: 4

Abstract

The rates of AlCl 3· CH 3 NO 2-catalyzed phenethylations of benzene (50° C) or toluene (25° C) with 2-arylethyl (ring-substituted phenethyl) chlorides were measured in homogeneous nitromethane solutions. The reactions are first-order in the aromatic component, first-order in the phenethyl chloride, and second-order in aluminum chloride. Substituent effects in the phenethyl chlorides give linear relationships with Hammett's σ ...

Related Articles:

Functional Group Tolerant Kumada− Corriu− Tamao Coupling of Nonactivated Alkyl Halides with Aryl and Heteroaryl Nucleophiles: Catalysis by a Nickel Pincer …

[Vechorkin, Oleg; Proust, Valerie; Hu, Xile Journal of the American Chemical Society, 2009 , vol. 131, # 28 p. 9756 - 9766]

Efficient Heterogeneously Palladium-Catalysed Synthesis of Stilbenes and Bibenzyls

[Cusati, Giuseppe; Wedig, Anja; Djakovitch, Laurent Letters in Organic Chemistry, 2009 , vol. 6, # 1 p. 77 - 81]

Stereoselective debromination and selective reduction of vic-dibromides with nickel boride

[Khurana, Jitender M.; Kandpal, Bhaskar M.; Kukreja, Gagan; Sharma, Purnima Canadian Journal of Chemistry, 2006 , vol. 84, # 8 p. 1019 - 1023]

New one-pot cross-coupling reaction between grignard reagents and alkoxymethyldiphenylphosphonium iodides in situ-formed from alcohols, …

[Shintou, Taichi; Kikuchi, Wataru; Mukaiyama, Teruaki Chemistry Letters, 2003 , vol. 32, # 8 p. 676 - 677]

Chemistry of the tert-butyl radical: polar character,. rho. value for reaction with toluenes, and the effect of radical polarity on the ratio of benzylic hydrogen abstraction to …

[Pryor, William A.; Tang, Felicia Y.; Tang, Robert H.; Church, Daniel F. Journal of the American Chemical Society, 1982 , vol. 104, # 10 p. 2885 - 2891]

More Articles...