Activation of C–H bonds of hydrocarbons by the ArH–alkali metal systems in THF (ArH–naphthalene, biphenyl, anthracene, phenanthrene, trans-stilbene, pyrene). …

…, MA Ilatovskaya, SM Yunusov, ES Kalyuzhnaya…

Index: Rummel; Ilatovskaya; Yunusov; Kalyuzhnaya; Shur Journal of Organometallic Chemistry, 2009 , vol. 694, # 9-10 p. 1459 - 1466

Full Text: HTML

Citation Number: 4

Abstract

Systems based on naphthalene and alkali metals (Li, Na, K) in THF are able to induce the alkylation of naphthalene with ethene at room temperature and atmospheric pressure. The highest activity in this reaction is exhibited by the naphthalene–potassium system which converts naphthalene into 1-ethylnaphthalene (1) and small amounts of two isomeric dihydro derivatives of 1 in a yield of 85%(24h, K: C10H8= 2: 1). The same alkylation ...

Related Articles:

Iron-catalyzed cross-coupling of aryltrimethylammonium triflates and alkyl Grignard reagents

[Guo, Wang-Jun; Wang, Zhong-Xia Tetrahedron, 2013 , vol. 69, # 46 p. 9580 - 9585]

Nickel-phosphine complex-catalyzed Grignard coupling. I. Cross-coupling of alkyl, aryl, and alkenyl Grignard reagents with aryl and alkenyl halides: General scope …

[Tamao,K. et al. Bulletin of the Chemical Society of Japan, 1976 , vol. 49, p. 1958 - 1969]

Tetraphosphine/palladium catalysed Suzuki cross-coupling reactions of aryl halides with alkylboronic acids

[Kondolff, Isabelle; Doucet, Henri; Santelli, Maurice Tetrahedron, 2004 , vol. 60, # 17 p. 3813 - 3818]

Synthesis of all-cis-3-(2-diphenylphosphinoethyl)-1, 2, 4-tris (diphenylphosphinomethyl) cyclopentane (Ditricyp) from dicyclopentadiene

[Kondolff, Isabelle; Feuerstein, Marie; Doucet, Henri; Santelli, Maurice Tetrahedron, 2007 , vol. 63, # 38 p. 9514 - 9521]

More Articles...