Chemistry Letters

DEFLUORINATIVE COUPLING REACTIONS OF gem-DIFLUOROOLEFINS WITH ORGANOLITHIUM REAGENTS. NOVEL, FACILE METHODS FOR CHAIN …

S Hayashi, T Nakai, N Ishikawa

Index: Hayashi, Sei-ichi; Nakai, Takeshi; Ishikawa, Nobuo Chemistry Letters, 1980 , p. 935 - 938

Full Text: HTML

Citation Number: 5

Abstract

Three types of coupling reactions of gem-difluoroolefins derived easily from aldehydes with lithium reagents (R′ Li and R′ 2 NLi) are described which constitute the facile procedures for conversions of aldehydes (RCHO) to amides (RCH 2 CONR′ 2), acetylenes (R–C≡ C– R′), and ketones (RCH 2 COR′).

Related Articles:

Rhodium-mediated alkylation of acid chlorides. A facile solid-state ketone synthesis using a recyclable polymer-bound rhodium complex

[Pittman,C.U.; Hanes,R.M. Journal of Organic Chemistry, 1977 , vol. 42, p. 1194 - 1197]

Physical properties of fatty acid methyl esters. II. Refractive index and molar refraction

[Whitmore; Sutherland; Cosby Journal of the American Chemical Society, 1942 , vol. 64, p. 1362]

Physical properties of fatty acid methyl esters. II. Refractive index and molar refraction

[Whitmore; Sutherland; Cosby Journal of the American Chemical Society, 1942 , vol. 64, p. 1362]

Convenient Syntheses of Functionalized Dialkyl Ketones and Alkanoylsilanes: 1-(Benzotriazol-1-yl)-1-phenoxyalkanes as Alkanoyl Anion Equivalents

[Katritzky, Alan R.; Lang, Hengyuan; Wang, Zuoquan; Lie, Zhu Journal of Organic Chemistry, 1996 , vol. 61, p. 7551 - 7557]

Cycloalkanones. 8. Hypocholesterolemic activity of long-chain ketones related to pentadecanone

[Wyrick; Hall; Piantadosi; Fenske Journal of Medicinal Chemistry, 1976 , vol. 19, # 2 p. 219 - 222]

More Articles...