The addition of fluorine to halogenated olefins by means of metal fluorides

DA Rausch, RA Davis, DW Osborne

Index: Rausch,D.A. et al. Journal of Organic Chemistry, 1963 , vol. 28, p. 494 - 497

Full Text: HTML

Citation Number: 14

Abstract

The selective addition of fluorine to the double bond of olefins by means of vapor phase reaction with cobalt trifluoride at 20-125'has been found to be quite general for stable halogenated olefins. Chloroethylene, cis-1, 2 dichloroethylene, trichloroethylene, 1, l- difluoroethylene, 2-bromo-l, l, l-trifluoropropene, and 2-fluoropropene produced the respective vicinal difluoro derivatives in fair yields. In addition, compounds produced by ...

Related Articles:

Fluorination of Hydrogen-containing with elemental fluorine

[Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C. Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326]

Bioactivation of S-(2, 2-dihalo-1, 1-difluoroethyl)-L-cysteines and S-(trihalovinyl)-L-cysteines by cysteine S-conjugate β-lyase: indications for formation of both …

[Commandeur, Jan N. M.; King, Laurence J.; Koymans, Luc; Vermeulen, Nico P. E. Chemical Research in Toxicology, 1996 , vol. 9, # 7 p. 1092 - 1102]

Fluorination of Hydrogen-containing with elemental fluorine

[Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C. Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326]

Fluorination of Hydrogen-containing with elemental fluorine

[Conte, L.; Gambaretto, G. P.; Napoli, M.; Gervasutti, C. Journal of Fluorine Chemistry, 1988 , vol. 38, p. 319 - 326]

540. Addition of free radicals to unsaturated systems. Part XIV. The direction of radical addition to trifluoroethylene

[Haszeldine; Steele Journal of the Chemical Society, 1957 , p. 2800,2806]

More Articles...