Organic & biomolecular chemistry

Stereoselective direct reductive amination of ketones with electron-deficient amines using Re 2 O 7/NaPF 6 catalyst

BG Das, P Ghorai

Index: Das, Braja Gopal; Ghorai, Prasanta Organic and Biomolecular Chemistry, 2013 , vol. 11, # 26 p. 4379 - 4382

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Citation Number: 4

Abstract

The first example of direct reductive amination (DRA) of ketones with electron-deficient amines (EDA) such as Cbz-, Boc-, EtOCO-, Fmoc-, Bz-, ArSO2-, etc. protected amines have been achieved using catalytic Re2O7/NaPF6. Excellent chemoselectivities as well as

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