Journal of Physical Chemistry

Laser-induced reactions of hexafluorobenzene and selected hydride compounds

Y Koga, R Chen, PM Keehn

Index: Koga, Yoshinori; Chen, Ruth; Keehn, Philip M. Journal of Physical Chemistry, 1987 , vol. 91, # 2 p. 306 - 311

Full Text: HTML

Citation Number: 3

Abstract

In the preceding paper'the reaction of C6F6/SiH4 mixtures was studied by single-pulse C 0 2 laser irradiation. We observed that the decomposition of C6F6 was substantially increased by the addition of silane. One of the possibilities for the significant increment in the decomposition of C6F6 in the laser-induced reaction with SiH4 could be related to the primary formation of pentafluorophenyl and fluorine radicals as follows:

Related Articles:

The radiation chemistry of acyclic hydrofluoro and perhalogenated ether and hydrocarbon compounds

[Journal of Fluorine Chemistry, , vol. 121, # 2 p. 153 - 162]

Isothermal pyrolysis of iodomethanes in gases

[Russian Journal of General Chemistry, , vol. 79, # 12 p. 2641 - 2651]

Infrared multiphoton decomposition of pentafluoroethane. Comments on multichannel dissociation

[Journal of Physical Chemistry, , vol. 84, # 15 p. 1873 - 1875]

Arrhenius parameters for the reaction of trifluoromethyl radicals with cyanogen chloride

[Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, , vol. 77, p. 253 - 260]

Arrhenius parameters for the reaction of trifluoromethyl radicals with cyanogen chloride

[Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, , vol. 77, p. 253 - 260]

More Articles...