Perfluorooctylation of aromatic compounds with perfluoroazooctane upon 185 nm irradiation in a two-phase system

T Nakamura, Y Koga

Index: Nakamura, Takako; Koga, Yoshinori Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 3 p. 659 - 662

Full Text: HTML

Citation Number: 14

Abstract

An efficient method for the preparation of perfluorooctylated aromatic and heteroaromatic compounds has been developed using photolysis of perfluoroazooctane (E)-1 upon 185 nm irradiation. The use of a two-phase system made up of a perfluorohexane solution of (E)-1 and a suitable aromatic compound has proved efficient for this reaction. The photolytic mechanism of (E)-1 upon 185 nm irradiation has also been investigated on the basis of ...

Related Articles:

Solvent effects on the reaction of perfluoroalkyl iodides and α, ω-perfluoroalkyl diiodides with cadmium powder and dimethylcadmium

[Nair, Haridasan K.; Burton, Donald J. Journal of Fluorine Chemistry, 1993 , vol. 60, # 1 p. 1 - 12]

Synthesis of perfluoroalkyl carboxylic acids by reaction of perfluoroalkyl iodides with electrogenerated superoxide ion

[Amatore, C. Journal of Fluorine Chemistry, 1991 , vol. 51, # 3 p. 357 - 379]

Building blocks for n-type molecular and polymeric electronics. Perfluoroalkyl-versus alkyl-functionalized oligothiophenes (nTs; n= 2-6). Systematic synthesis, …

[Chen, Grace J.; Tamborski, Christ Journal of Fluorine Chemistry, 1987 , vol. 36, p. 123 - 140]

Building blocks for n-type molecular and polymeric electronics. Perfluoroalkyl-versus alkyl-functionalized oligothiophenes (nTs; n= 2-6). Systematic synthesis, …

[Chen, Grace J.; Tamborski, Christ Journal of Fluorine Chemistry, 1987 , vol. 36, p. 123 - 140]

Direct perfluoroalkylation of functionalized benzenes with perfluoroalkyl halides and copper bronze

[Fuchikami, Takamasa; Ojima, Iwao Journal of Fluorine Chemistry, 1983 , vol. 22, p. 541 - 556]

More Articles...