PNAS 2007-02-27

Effect of carbonates/phosphates as nucleophilic catalysts in dimethylformamide for efficient cyanosilylation of aldehydes and ketones.

G K Surya Prakash, Habiba Vaghoo, Chiradeep Panja, Vijayalakshmi Surampudi, Roman Kultyshev, Thomas Mathew, George A Olah

Index: Proc. Natl. Acad. Sci. U. S. A. 104(9) , 3026-30, (2007)

Full Text: HTML

Abstract

Cyanosilylation of aldehydes and aliphatic ketones can be carried out in dimethylformamide even without the use of any catalyst. In the presence of nucleophilic catalysts such as carbonate and phosphate salts, the reaction rate is significantly enhanced.

Related Compounds

  • Trimethylsilyl cya...

Related Articles:

Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines.

2007-01-01

[Angew. Chem. Int. Ed. Engl. 46(44) , 8468-70, (2007)]

A chemoselective Ugi-type reaction in water using TMSCN as a functional isonitrile equivalent: generation of heteroaromatic molecular diversity.

2012-12-14

[Org. Biomol. Chem. 10(46) , 9271-7, (2012)]

Sc₂(pydc)₂ unit based 1D, 2D and 3D metal-organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation.

2015-01-28

[Dalton Trans. 44(4) , 1942-7, (2014)]

Facile and efficient enantioselective Strecker reaction of ketimines by chiral sodium phosphate.

2009-06-08

[Chemistry 15(24) , 6008-14, (2009)]

Synthesis of homo-N-nucleoside with 1,2,4-triazole-3-carboxamide.

2005-01-01

[Nucleosides Nucleotides Nucleic Acids 24(5-7) , 979-81, (2005)]

More Articles...