Journal of fluorine chemistry

Reaction of bis (trifluoromethyl) amino-oxyl with alkylchlorosilanes and allyldichloro (methyl) silane and of perfluoro-2, 5-diazahexane 2, 5-dioxyl with vinylsilanes and …

AE Tipping, RB Yadav

Index: Tipping, Anthony E.; Yadav, Rajendraprasad B. Journal of Fluorine Chemistry, 1994 , vol. 68, # 1 p. 1 - 10

Full Text: HTML

Citation Number: 0

Abstract

Abstract Treatment of the silanes MeSiHCl 2, Me 2 SiHCl and EtSiMeCl 2 with the oxyl (CF 3) 2 NO·(1) gives the substitution products (CF 3) 2 NOSiMeCl 2 (4) and (CF 3) 2 NOSiMe 2 Cl (5), and a mixture of (CF 3) 2 NOCHMeSiMeCl 2 (8) and (CF 3) 2 NOCH 2 CH 2 SiMeCl 2 (9)(ratio 20: 37), respectively, while the silane EtSiMe 2 Cl affords mainly the ester (CF 3) 2 NO 2 CMe (7). Attack of oxyl 1 on the silane CH 2= CHCH2SiMeCl 2 results in both allylic ...

Related Articles:

Perfluoroalkylation of simple inorganic molecules: A one step route to novel perfluoroalkylated compounds

[Singh, Rajendra P.; Shreeve, Jean'ne M. Chemical Communications, 2002 , # 17 p. 1818 - 1819]

On the reaction of perfluoro-aza-propene with oxygen difluoride and fluorination of bis (trifluoromethyl)-hydroxylamine

[Minkwitz, Rolf; Reinemann, Stefan; Ludwig, Ralf Journal of Fluorine Chemistry, 1999 , vol. 99, # 2 p. 145 - 149]

Generation of 15N labelled bis (polyfluoroalkyl) nitroxides and their hydrogen-abstraction reactions with alkanes, alkylbenzenes and aldehydes

[Zhao, Cheng-Xue; Chen, Guo-Fei; Jiang, Xi-Kui Journal of Fluorine Chemistry, 1988 , vol. 38, p. 391 - 398]

On the reaction of perfluoro-aza-propene with oxygen difluoride and fluorination of bis (trifluoromethyl)-hydroxylamine

[Minkwitz, Rolf; Reinemann, Stefan; Ludwig, Ralf Journal of Fluorine Chemistry, 1999 , vol. 99, # 2 p. 145 - 149]

Fluorinated acetylenes. Part 8 [1]. Preparation and some reactions of 5, 5, 5-trifluoropent-3-yn-2-ol, 5, 5, 5-trifluoro-1-phenylpent-3-yn-2-ol and the derived ester, 2- …

[Sibous, Lakhdar; Tipping, Anthony E. Journal of Fluorine Chemistry, 1993 , vol. 62, # 1 p. 39 - 49]

More Articles...