Solid??State and Solution Structures of a Series of [(HBPz3Me2) Rh (CO)(PR3)] and [(HBPz3Me2, 4Cl) Rh (CO)(PR3)] Complexes

…, SL Berre, M Etienne, JC Daran, P Kalck

Index: Malbosc, Francois; Chauby, Valerie; Serra-Le Berre, Carole; Etienne, Michel; Daran, Jean-Claude; Kalck, Philippe European Journal of Inorganic Chemistry, 2001 , # 10 p. 2689 - 2697

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Citation Number: 19

Abstract

Abstract Addition of 1 equiv. of a phosphane or phosphite ligand to the κ 3-bonded [Tp Me2 Rh (CO) 2] and [Tp Me2, 4Cl Rh (CO) 2] dicarbonyl precursors gives the monosubstituted complexes [TpRh (CO) L]. The X-ray crystal structures show that the three complexes [Tp Me2 Rh (CO)(PMe 3)],[Tp Me2 Rh (CO)(PMePh 2)], and [Tp Me2, 4Cl Rh (CO)(PMePh 2)] adopt square-planar geometries. The X-ray crystal structure of [Tp Me2 Rh (CO){P (OPh) 3 ...