Diastereoselective. alpha. allylation of secondary and tertiary thioamides via thio-Claisen rearrangement. A structural proof of Z secondary thioamide dianions and Z …

Y Tamaru, Y Furukawa, M Mizutani…

Index: Journal of Organic Chemistry, , vol. 48, # 21 p. 3631 - 3639

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Citation Number: 34

Abstract

... Par- ticularly the methodology based on the enolate chemistry 0 1983 American Chemical Society Page 2. ... a-Allylation of Secondary and Tertiary Thioamides J. Org. ... (12) Fleming, I. 'Frontier Orbitals and Organic Chemical Reactions"; Wiley: New York, 1976; Chapter 4-1-3. ...

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