Chemical Communications 2002-03-21

Remarkable co-catalysis by copper(I) oxide in the palladium catalyzed cross-coupling of arylboronic acids with ethyl bromoacetate.

Xing-xin Liu, Min-zhi Deng

Index: Chem. Commun. (Camb.) (6) , 622-3, (2002)

Full Text: HTML

Abstract

Copper(I) oxide can effectively co-catalyze the Suzuki type cross-coupling reactions of arylboronic acids with ethyl bromoacetate. As an alternative protocol for introducing the methylenecarboxy group into functionalized molecules, this reaction occurs in the absence of highly toxic thallium compounds or special ligands and should be convenient and practical.

Related Compounds

  • ethyl 2-bromoaceta...

Related Articles:

Preoperative Detection and Intraoperative Visualization of Brain Tumors for More Precise Surgery: A New Dual-Modality MRI and NIR Nanoprobe.

2015-09-16

[Small 11 , 4517-25, (2015)]

Design and synthesis of a novel pre-column derivatization reagent with a 6-methoxy-4-quinolone moiety for fluorescence and tandem mass spectrometric detection and its application to chiral amino acid analysis.

2015-12-10

[J. Pharm. Biomed. Anal. 116 , 71-9, (2015)]

Transient receptor potential ankyrin 1 (TRPA1) channel as emerging target for novel analgesics and anti-inflammatory agents.

2010-07-22

[J. Med. Chem. 53 , 5085-107, (2010)]

Preparing a pseudo-solid by the reinforcement of a polydentate thioether using silver nanoparticles.

2015-02-07

[Nanoscale 7(5) , 1977-83, (2015)]

Mixture toxicity of S(N)2-reactive soft electrophiles: 2-evaluation of mixtures containing ethyl α-halogenated acetates.

2011-11-01

[Arch. Environ. Contam. Toxicol. 61(4) , 547-57, (2011)]

More Articles...