Organic Letters 2012-02-17

An alternative approach to para-C-H arylation of phenol: palladium-catalyzed tandem γ-arylation/aromatization of 2-cyclohexen-1-one derivatives.

Tatsushi Imahori, Toru Tokuda, Tatsuya Taguchi, Hiroki Takahata

Index: Org. Lett. 14(4) , 1172-5, (2012)

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Abstract

An efficient approach to prepare para-aryl phenols has been developed by using a Pd-catalyzed tandem γ-arylation/aromatization of 2-cyclohexen-1-one derivatives with aryl bromides. This approach provides various p-aryl phenols from the phenol surrogates, 2-cyclohexen-1-one derivatives, in a single reaction step on the basis of C-H arylation.

Related Compounds

  • cyclohexenone

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