Preparation and reactions of 5-aryl-1, 4, 2-dithiazolium salts.

K Yonemoto, I Shibuya, T Tsuchiya…

Index: Yonemoto, Katsumi; Shibuya, Isao; Tsuchiya, Tohru; Masahiko Yasumoto; Taguchi, Yoichi Bulletin of the Chemical Society of Japan, 1990 , vol. 63, # 10 p. 2933 - 2937

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Citation Number: 10

Abstract

S-Thioaroylsulfenamides (ArCSSNH 2), formed by reaction of ArCSS− Na+ with hydroxylamine-O-sulfonic acid, were aroylated or acylated to give N-aroyl-or N-acyl-S- thioaroylsulfenamides, respectively, which were then cyclized with dehydration to afford 3- substituted 5-aryl-1, 4, 2-dithiazolium salts. The behavior of 3, 5-diphenyl-1, 4, 2-dithiazolium perchlorate toward nucleophiles such as active methylene and amino compounds was ...

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