Ruthenium-catalyzed redox isomerization/transfer hydrogenation in organic and aqueous media: A one-pot tandem process for the reduction of allylic alcohols

…, P Crochet, J Francos, SE García-Garrido, J Gimeno…

Index: Cadierno, Victorio; Crochet, Pascale; Francos, Javier; Garcia-Garrido, Sergio E.; Gimeno, Jose; Nebra, Noel Green Chemistry, 2009 , vol. 11, # 12 p. 1992 - 2000

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Citation Number: 58

Abstract

The hexamethylbenzene-ruthenium (II) dimer [{RuCl (μ-Cl)(η6-C6Me6)} 2] 1 and the mononuclear bis (allyl)-ruthenium (IV) complex [RuCl2 (η3: η2: η3-C12H18)] 2, associated with base and a hydrogen donor, were found to be active catalysts for the selective reduction of the CC bond of allylic alcohols both in organic and aqueous media. The process, which proceeds in a one-pot manner, involves a sequence of two independent reactions:(i) the ...

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