Vanadium (V) complexes of polydentate amino alcohols: Fine-tuning complex properties

DC Crans, I Boukhobza

Index: Crans, Debbie C.; Boukhobza, Iman Journal of the American Chemical Society, 1998 , vol. 120, # 32 p. 8069 - 8078

Full Text: HTML

Citation Number: 32

Abstract

In aqueous solution, the stability, the structure, and the lability of 12 vanadium (V) complexes were determined and related to the amino alcohol ligand properties. The amino alcohols were chosen to maintain a five-coordinate vanadium geometry in the vanadium complex and were based on diethanolamine as the parent ligand. Apparent and composite stability constants were determined for all 12 complexes. Selected complexes were further ...