… AND ELECTRONIC INTERACTION STUDIES OF α-SUBSTITUTED CARBONYL COMPOUNDS. VI. p-SUBSTITUTED α-PHENYLTHIOACETONES

PR Olivato, SA Guerrero…

Index: Olivato, Paulo R.; Guerrero, Sandra A.; Martins, Elizabeth A. L. Phosphorus, Sulfur and Silicon and the Related Elements, 1989 , vol. 44, p. 9 - 16

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Citation Number: 10

Abstract

Abstract The analysis of the v co bands in the IR spectrum of p-substituted α- phenylthioacetones indicates a cis/gauche rotational isomerism. The slight solvent effect on the αc/αg ratios on going from a non polar solvent to a polar one, for the title compounds, as well as the minute sensitivity of the v co (cis) frequencies on going from electron-attracting to electron-donating substituents are interpreted on the grounds of the Field (F) and ...

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