Flash vacuum thermolysis of 1, 3-dioxolan-4-ones

TB Cameron, FM El-Kabbani…

Index: Cameron, Tim B.; El-Kabbani, Fiesal M.; Pinnick, Harold W. Journal of the American Chemical Society, 1981 , vol. 103, # 18 p. 5414 - 5417

Full Text: HTML

Citation Number: 9

Abstract

Abstract: Flash vacuum thermolysis of 1, 3-dioxolan-4-ones yields aldehydes and ketones as the major products as the result of apparent decarbonylation of a lactones formed by collapse of a 1, 3 dipole. When phenyl substituents are present, epoxides are also formed via the intermediacy of a carbonyl ylide.

Related Articles:

Superoxide dismutase mimetics. Part 2: synthesis and structure–Activity relationship of glyoxylate-and glyoxamide-Derived metalloporphyrins

[Bioorganic and Medicinal Chemistry, , vol. 11, # 13 p. 2695 - 2707]

Total synthesis of the antibiotic sparsomycin, a modified uracil amino acid monoxodithioacetal

[Journal of Organic Chemistry, , vol. 46, # 16 p. 3273 - 3283]

Photodegradation of butyl acrylate in the troposphere by OH radicals: kinetics and fate of 1, 2??hydroxyalcoxy radicals

[Journal of Physical Organic Chemistry, , vol. 21, # 5 p. 397 - 401]

Notes-A Convenient Method for Reduction of Hydroperoxide Ozonation Products

[Journal of Organic Chemistry, , vol. 25, p. 1031 - 1033]

Flash vacuum thermolysis of 1, 3-dioxolan-4-ones

[Journal of the American Chemical Society, , vol. 103, # 18 p. 5414 - 5417]

More Articles...