The Journal of Organic Chemistry

Preparation of. alpha.-halo sulfoximines

CR Johnson, HG Corkins

Index: Johnson,C.R.; Corkins,H.G. Journal of Organic Chemistry, 1978 , vol. 43, p. 4136 - 4140

Full Text: HTML

Citation Number: 15

Abstract

(?-Halo sulfoximines have been prepared by the chlorination of N-methyl-and N- chlorosulfoximines with tert: butyl hypochlorite (BHC) and by amination of cu-halo sulfoxides with mesitylsulfonyloxyamine. cu-Chlorination of S-tiutyl-lL, S-dimethylsulfoximine with BHC occurred only at the S-methyl. Reaction of S-butyl-or S-ethyl-N-methvl-S-phenylsulfoximine with RHC gave a single diastereomer.

Related Articles:

Total synthesis of spatane diterpenes: the tricyclic nucleus

[Salomon; Sachinvala; Roy; Basu; Raychaudhuri; Miller; Sharma Journal of the American Chemical Society, 1991 , vol. 113, # 8 p. 3085 - 3095]

Determination of absolute configuration using density functional theory calculations of optical rotation and electronic circular dichroism: chiral alkenes

[Johnson, Carl R.; Barbachyn, Michael R. Journal of the American Chemical Society, 1982 , vol. 104, # 15 p. 4290 - 4291]

Synthesis of chiral sulfoximine-based thioureas and their application in asymmetric organocatalysis

[Frings, Marcus; Thome, Isabelle; Bolm, Carsten Beilstein Journal of Organic Chemistry, 2012 , vol. 8, p. 1443 - 1451]

Total syntheses of the sesquiterpenoids (+)-trans-dracunculifoliol and (+)-4-hydroxyoppositan-7-one

[Oballa, Renata M.; Carson, Rebekah; Lait, Susan; Cadieux, Jay A.; Robichaud, Joel Tetrahedron, 2005 , vol. 61, # 11 p. 2761 - 2766]

Determination of absolute configuration using density functional theory calculations of optical rotation and electronic circular dichroism: chiral alkenes

[Johnson, Carl R.; Barbachyn, Michael R. Journal of the American Chemical Society, 1982 , vol. 104, # 15 p. 4290 - 4291]

More Articles...