Carbohydrate Research 2003-10-31

High yield regioselective monobenzyloxycarbonylation of secondary alcohols in glycopyranoside series.

Alain Morère, Fouzi Mouffouk, Audrey Jeanjean, Alain Leydet, Jean-Louis Montero

Index: Carbohydr. Res. 338(22) , 2409-12, (2003)

Full Text: HTML

Abstract

The regioselective monobenzyloxycarbonylation of secondary alcohols in methyl 6-O-(4-methoxytrityl)-alpha-D-manno-, gluco- and galactopyranoside has been achieved in high yields (74-85%) by using benzyl chloroformate in the presence of 4-dimethylaminopyridine and/or 1,4-diazabicyclo[2.2.2]octane.

Related Compounds

  • Benzyl chloroforma...

Related Articles:

Polymeric micelles for pH-responsive delivery of cisplatin.

2014-08-01

[J. Drug Target. 22(7) , 629-37, (2014)]

Ames Salmonella/mammalian-microsome testing of peptides and peptide synthesis reagents.

1986-01-01

[Mutat. Res. 170(1-2) , 23-9, (1986)]

Untargeted metabolomics in doping control: detection of new markers of testosterone misuse by ultrahigh performance liquid chromatography coupled to high-resolution mass spectrometry.

2015-08-18

[Anal. Chem. 87 , 8373-80, (2015)]

Curtius rearrangement of aromatic carboxylic acids to access protected anilines and aromatic ureas.

2006-12-07

[Org. Lett. 8 , 5717, (2006)]

Synthesis, colon-targeted studies and pharmacological evaluation of an anti-ulcerative colitis drug 4-Aminosalicylic acid-β-O-glucoside.

2016-01-27

[Eur. J. Med. Chem. 108 , 486-94, (2016)]

More Articles...