Catalytic [3+ 2] annulation of aminocyclopropanes for the enantiospecific synthesis of cyclopentylamines

F de Nanteuil, J Waser

Index: De Nanteuil, Florian; Waser, Jerome Angewandte Chemie - International Edition, 2011 , vol. 50, # 50 p. 12075 - 12079

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Citation Number: 81

Abstract

Cyclic structures are encountered in the core of most bioactive synthetic and natural products. Carbo-and heterocyclic rings give rigidity to molecules, thus fixing the spatial arrangement of the functional groups. As a result, specific interactions with biomolecules without important entropy costs become possible. Nitrogen-based functional groups are especially important in synthetic and medicinal chemistry. In this respect, ...

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