Organic letters

Co-Catalyzed Synthesis of 1, 4-Dicarbonyl Compounds Using TBHP Oxidant

F Zhang, P Du, J Chen, H Wang, Q Luo, X Wan

Index: Zhang, Feng; Du, Peng; Chen, Jijun; Wang, Hongxiang; Luo, Qiang; Wan, Xiaobing Organic Letters, 2014 , vol. 16, # 7 p. 1932 - 1935

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Citation Number: 30

Abstract

A Co-catalyzed reaction for the construction of 1, 4-dicarbonyls has been reported in which cascade organocobalt addition/trapping/Kornblum–DeLaMare rearrangement were involved. In view of the easy availability of starting materials, wide substrate scope, high functionality tolerance, and operational simplicity, this protocol constituted a simple, practical, and powerful alternative compared with previous approaches.

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