Chemische Berichte

Über die doppelte Mannich??Kondensation mit cyclischen Ketonen sowie über α. α′??Dimethylen??cycloalkanone

M Mühlstädt

Index: Muehlstaedt,M. Chemische Berichte, 1960 , vol. 93, p. 2638 - 2648

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Citation Number: 3

Abstract

Abstract Bei der Umsetzung von Cycloalkanonen (C 5 [BOND] C 7) oder der entsprechenden Mono-Mannich-Basen-Hydrochloride mit Formalin und sekundären Aminhydrochloriden entstanden Bis-dialkylaminomethyl-cycloalkanon-dihydrochloride, deren symm. Struktur durch Spaltung in α. α′-Dimethylen-cycloalkanone bewiesen wurde. Cyclohexadecanon gab nur Mono-Basenhydrochlorid.–Die leicht polymerisierenden ...

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