Reactions of the free toluene-p-sulphonyl radical. Part I. Diagnostic reactions of free radicals

CMM da Silva Corrêa, WA Waters

Index: da Silva Correa,C.M.M.; Waters,W.A. Journal of the Chemical Society [Section] C: Organic, 1968 , p. 1874 - 1879

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Citation Number: 17

Abstract

The free p· CH3· C6H4· SO2 radical is easily produced by the thermolysis or photolysis of p· Me· C6H4· SO2· l; copper powder assists the removal of iodine and so do radicals R2C (CN)·. Evidence is presented to show that p· Me· C6H4· SO2· l adds homolytically to olefins and that free p· Me· C6H4· SO2· radicals tend to disproportionate according to the equation: 6 Me· C6H4· SO2·→ 2 (Me· C6H4· SO2) 2O+ Me· C6H4· S· SO2· C6H4· Me p· Me· C6H4· ...

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