Inorganic Chemistry 2005-06-27

A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains.

Jin-Tang Li, Jun Tao, Rong-Bin Huang, Lan-Sun Zheng, Tan Yuen, C L Lin, Princy Varughese, Jing Li

Index: Inorg. Chem. 44(13) , 4448-50, (2005)

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Abstract

A three-dimensional coordination polymer, [Mn3(OH)2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

Related Compounds

  • 3-Cyanobenzoic aci...

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