Racemic and optically active 1, 1′??binaphthyl??2, 2′??diyl sulfite: Synthesis, crystal structure, and ring??opening reactions with selected nucleophiles

…, B Marciniak, E Rozycka??Sokolowska

Index: Drabowicz, Jozef; Krasowska, Dorota; Marciniak, Bernard; Rozycka-Sokolowska, Ewa Heteroatom Chemistry, 2011 , vol. 22, # 3-4 p. 562 - 570

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Abstract

Abstract Preparation of the sulfite derived from racemic and (R)−(+)-enantiomer of BINOL is reported. The crystal structure of the optically active, levorotatory sulfite isomer and its ring opening induced by nucleophilic substitution reactions with selected nucleophiles are presented.© 2011 Wiley Periodicals, Inc. Heteroatom Chem 22: 562–570, 2011; View this article online at wileyonlinelibrary. com. DOI 10.1002/hc. 20722

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