Tetrahedron

Stereoselective allylation of chiral monoperoxyacetals

A Ahmed, PH Dussault

Index: Ahmed, Aqeel; Dussault, Patrick H. Tetrahedron, 2005 , vol. 61, # 19 p. 4657 - 4670

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Citation Number: 14

Abstract

Neighboring iodo-, alkoxy-, acetoxy-and silyl groups impart useful levels of diastereoselection in the Lewis acid-mediated allylation of monoperoxyacetals. Although monoperoxyacetals are found to be considerably less reactive than corresponding nonperoxidic acetals, similar stereochemical trends are observed in the two series.

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