α, β-Epoxy sulfoxides and sulfones. Synthesis and some reactions
T Durst, KC Tin, FD Reinach-Hirtzbach…
Index: Durst,T. et al. Canadian Journal of Chemistry, 1979 , vol. 57, p. 258 - 266
Full Text: HTML
Citation Number: 53
Abstract
A number of α, β-epoxy sulfoxides and epoxy sulfones have been prepared via cyclization of α-chloro-β-hydroxy sulfoxides or phase-transfer catalyzed reaction between α-chloroalkyl sulfones and carbonyl compounds. Thermal and acid-catalyzed rearrangement of these epoxides resulted in migration of sulfinyl or sulfonyl groups to form β-carbonyl sulfoxides or sulfones. Upon treatment of the epoxy sulfones with MgBr2 in ether, α-bromocarbonyl ...
Related Articles:
[Darmanyan, Alexander P.; Gregory, Daniel D.; Guo, Yushen; Jenks, William S. Journal of Physical Chemistry A, 1997 , vol. 101, # 37 p. 6855 - 6863]
[Darmanyan, Alexander P.; Gregory, Daniel D.; Guo, Yushen; Jenks, William S. Journal of Physical Chemistry A, 1997 , vol. 101, # 37 p. 6855 - 6863]
[Darmanyan, Alexander P.; Gregory, Daniel D.; Guo, Yushen; Jenks, William S. Journal of Physical Chemistry A, 1997 , vol. 101, # 37 p. 6855 - 6863]