Journal of the American Chemical Society

Effect of structure on reactivity. IX. A study of the aminolysis of esters of trichloro-and trifluoroacetic acids

MM Joullié, AR Day

Index: Joullie; Day Journal of the American Chemical Society, 1954 , vol. 76, p. 2990,2992

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Citation Number: 19

Abstract

Other anionic reagents, with few exceptions, have not been studied. Concentrated aqueous ammonia converts ethyl trichloroacetate to trichloroacetamide in poor yields2 The fact that no chloroform was reported is somewhat surprising since the trichloromethyl group would be expected to cleave very readily. In view of this apparent anomaly, it was decided to study the reactions of ammonia, primary amines and secondary amines with esters of trihalogen ...

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