Photochemical reactions of vinyl-, styryl-, and benzyl-substituted digermanes

K Mochida, H Kikkawa, Y Nakadaira

Index: Mochida, Kunio; Kikkawa, Haruhiko; Nakadaira, Yasuhiro Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 9 p. 2772 - 2777

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Citation Number: 6

Abstract

Photochemical reactions of vinyl-, styryl-, and benzyl-substituted digermanes were investigated by chemical trapping experiments. Photolysis of vinylpentamethyldigermane afforded 1-trimethyl-2-(pentamethyldigermyl) ethane as a major product, and styrylpentamethyldigermanes gave mainly styryltrimethylgermane. On the other hand, photolysis of benzyl-substituted digermanes (benzylpentamethyldigermane and 1, 2- ...

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